Microplastics (MPs) distribution in Surface Sediments of the Freidounkenar Paddy Wetland.

There is an urgent need to increase knowledge on the distribution of microplastics (MPs) in wetlands because these are sites of special ecological value and the ever-growing use of plastic can threaten such fragile ecosystems. This research assesses, for the first time, the occurrence of MPs in surface sediment of the Freidounkenar International Wetland (Northern Iran), a valuable habitat for migratory birds. A total of 1368 MP/kg were identified in the surface sediments of the wetland. The distribution of MPs in sediments per area was Ezbaran (36.5%), Western Sorkhrood (32.0%), Freidounkenar (20.1%) and Eastern Sorkhrood Ab-bandans (11.4%). The most contaminated sites were located close to agricultural fields, Damgahs (agroecosystems for birds), fishing areas and roads. Fibers and white-transparent and black-grey MPs constituted the dominant MPs in the surface sediment. The most abundant MPs were < 250 µm and these were made of nylon, polypropylene-low density polyethylene copolymer, polystyrene, low density polyethylene and polypropylene. The identification of MPs was carried out visually and supported with Scanning Electron Microscopy (SEM)-Energy Dispersive X-Ray (EDX) and micro-Raman techniques. There were weathering signs in large proportion of the MPs, according to SEM analysis, which evidences their formation from the degradation of other plastics. This is a comprehensive study on MPs in surface sediment of this sensitive internationally recognized ecosystem with high ecological value.

Novel Combination of Silver Nanoparticles and Carbon Nanotubes for Plasmonic Photo Thermal Therapy in Melanoma Cancer Model.

Purpose: Plasmonic photo thermal therapy (PPTT) is a therapeutic method in which the photon energy is rapidly transformed into heat via a series of radiative and non-radiative phenomena to ablate cancer. Plasmonic NPs, such as silver NPs (Ag NPs), have considerable properties in optical absorbance. Furthermore, good thermal conductivity and cell penetration ability of carbon nanotubes (CNTs) could improve the efficacy of Ag NPs for PPTT. Decoration of the multi-walled carbon nanotubes (MWCNTs) with silver has been developed to enhance thermal conductivity of the MWCNT particles. Methods: The Ag NPs were decorated on the CNTs and the ability of these particles (CNT/Ag NPs) in reduction of melanoma tumor size after PTT was evaluated experimentally. For comparison, the PTT of silver nanorods (Ag NRs) and CNTs were investigated. The melanoma tumor was induced by injection of B16/F10 cell line to the inbred mice. Different NPs were injected into the tumors and then irradiated via laser diode (λ=670 nm, P=500 mW, and I= 3.5 W/cm2) at scheduled time. Results: Monitoring of tumor sizes showed that integration of CNTs with silver could enhance the optical absorption of CNTs and improve tumor destruction in PPTT technique. Conclusion: The CNT/Ag NPs could act as a potent agent in PPTT method in curing solid tumors.

A study on the tensile properties of silicone rubber/polypropylene fibers/silica hybrid nanocomposites.

Metacarpophalangeal joint implants have been usually made of silicone rubber. In the current study, silica nano particles and polypropylene fibers were added to silicone rubber to improve silicone properties. The effect of the addition of silica nano particles and polypropylene fibers on the tensile behavior of the resultant composites were investigated. Composite samples with different content of PP fibers and Silica nano particles (i. e. 0, 1 and 2wt%) as well as the hybrid composite of silicone rubber with 1wt% SiO2 and 1wt% PP fiber were prepared. Tensile tests were done at constant cross head speed. To study the body fluid effect on the mechanical properties of silicone rubber composites, samples soaked in simulated body fluid (SBF) at 37°C were also tested. The morphology of the samples were studied by scanning electron microscope. Results of analysis revealed that an increase in PP fibers and silica nano particles content to 2wt%, increases the tensile strength of silicone rubber of about 75% and 42% respectively. It was found out that the strength of the samples decreases after being soaked in simulated body fluid, though composites with PP fibers as the reinforcement showed less property degradation.

Incorporation of CPP-ACP into Luting and Lining GIC: Influence on Wear Rate (in the Presence of Artificial Saliva) and Compressive Strength.

The improvement of mechanical and antibacterial properties of glass ionomer cements (GICs) is an important goal in dental research. In this way, modification of GIC with caries preventive and remineralizing materials such as casein phosphopeptide-amorphous calcium phosphate (CPP-ACP) is a new strategy to enhance its anticariogenic properties and the remineralization of teeth. However, one main concern is that adding CPP-ACP may have negative effects on the mechanical properties of GIC. This study investigated the influence of adding CPP-ACP on the wear rate (in the presence of artificial saliva) and compressive strength of luting and lining glass ionomer cement. CPP-ACP was incorporated into a luting and lining glass ionomer cement at different percentages (1, 1.56, and 2%). Wear rate and compressive strength were measured for each group using Pin-on-Disk tribometer device (in artificial saliva condition) and universal testing machine, respectively. The wear test was carried out in the presence of artificial saliva for better simulation of the oral environment. Our results demonstrated that increasing the percentage of CPP-ACP from 0 up to 1.56% (w/w), caused a decrease of 19% in the wear rate. However, at 2% (w/w) CPP-ACP, the wear rate increased. Compressive strength was improved by 31% when the CPP-ACP concentration was increased to 1.56% (w/w), but decreased when the concentration was raised to 2% (w/w). In conclusion, adding 1.56% CPP-ACP into luting and lining glass ionomer cement appears to provide an acceptable combination of two important mechanical properties, compressive strength and wear rate.

Effect of nano silica on setting time and physical properties of mineral trioxide aggregate.

INTRODUCTION: Mineral trioxide aggregate (MTA) has been widely used in all fields of endodontics. One of the major drawbacks of this material is the long setting time. MTA is primarily composed of type 1 Portland cement and bismuth oxide. In cement, nanoscale SiO2 behaves as a filler to improve microstructure and to accelerate hydration process. The aforementioned reaction is also expected in MTA because of the same structure. Thus, the aim of this study was to evaluate the effect of addition of nano-SiO2 to MTA on the setting time and its physical properties. METHODS: Two concentrations (8% and 10%) of nano-SiO2 were added to the white MTA powder. After mixing with water, the setting time, compressive strength, and flexural strength were investigated and compared with pure MTA. RESULTS: With the addition of 8% and 10% of nano-SiO2 to the MTA, the setting time of both mixtures decreased significantly (P < .05). However, the compressive strength (after 1 day and 1 week) and flexural strength increased; this was not significant (P > .05). There was no significant difference between MTA mixed with 8% and 10% nano-SiO2 in setting time, compressive strength, and flexural strength (P > .05). CONCLUSIONS: The addition of 8% and 10% of nano-SiO2 to MTA accelerated the hydration process, reduced the setting time, and had no adverse effect on the compressive and flexural strength of MTA.

Pain reduction after initial archwire placement in orthodontic patients: a randomized clinical trial.

INTRODUCTION: The aim of this study was to compare the efficacy of ibuprofen, viscoelastic bite wafers, and chewing gum in reducing orthodontic pain. METHODS: This randomized clinical trial included 50 girls between the ages of 13 and 18 years classified into 5 groups of 10 each: placebo, ibuprofen (400 mg), chewing gum, soft viscoelastic wafer, and hard viscoelastic wafer. The patients in each group received 1 method immediately after placement of the initial archwires and every 8 hours if they experienced pain. Pain perception was recorded by the patients while chewing, biting, fitting front teeth, and fitting posterior teeth at 2 hours, 6 hours, bedtime, 24 hours, 2 days, 3 days, and 7 days after archwire placement, using a visual analog scale. Analysis of variance (ANOVA) and Tukey tests were used for data analysis. RESULTS: There were significant differences in pain perception of chewing function between the placebo group and the chewing-gum group at 24 hours and 7 days, and between the placebo group and the hard-viscoelastic group on the day 7 (P <0.05). Also, there were significant differences between the placebo group and the soft-viscoelastic group, and between the placebo group and the hard-viscoelastic group in pain severity when fitting posterior teeth at 6 hours (P <0.05). At other times and with other functions, no significant differences were recorded. CONCLUSIONS: Both chewing gum and viscoelastic bite wafers are effective for pain reduction in orthodontic patients and can be recommended as suitable substitutes for ibuprofen.

Effects of a simulated oral environment and sterilization on load-deflection properties of superelastic nickel titanium-based orthodontic wires.

UNLABELLED: The aim of this study was to evaluate the load-deflection characteristics of three types of nickel-titanium wires and investigate the effects of recycling on superelastic properties of them. MATERIALS AND METHODS: Thirty specimens for any of the single-strand Ni-Ti (Rematitan "Lite'), multi-strand Ni-Ti (SPEED Supercable) and Copper Ni-Ti (Damon Copper Ni-Ti) were tested. Ten specimens of each wire were subjected to three point bending test in the as-received condition (T0). The remaining wires were kept in a simulated oral environment for 2 months. Then, half of these specimens were tested for their load-deflection properties (T1), while the others were autoclave sterilized before testing (T2). Statistical analysis was performed by one-way ANOVA and Tukey test. RESULTS: Rematitan "Lite"showed significantly greater force than Damon Copper Ni- Ti and Damon Copper Ni-Ti, demonstrated significantly greater force than Supercable (p < 0.05). The effect of recycling on bending properties of nickel-titanium wires was significant (p < 0.05). T1 wires were generally associated with significantly lower forces than T0 specimens in deflections less than 2.0 mm, while load-deflection characteristics of T2 wires were not considerably different from those of T0 specimens. CONCLUSIONS: Supercable is useful when very light force is needed during orthodontic treatment, for example in severe crowding cases and traumatized teeth. Damon Copper Ni-Ti may be suitable for routine orthodontic treatment in adolescent and adult patients. It is suggested that clinicians who want to recycle nickel-titanium wires use autoclave sterilization.